nomenclature fragrantica.   While life continues in a pandemic of shifting scales and severity, we have perhaps not wandered into this century’s reprisal of the Roaring Twenties that sociologists and influencers alike anticipated in life after lockdown. nomenclature fragrantica

 
   While life continues in a pandemic of shifting scales and severity, we have perhaps not wandered into this century’s reprisal of the Roaring Twenties that sociologists and influencers alike anticipated in life after lockdownnomenclature fragrantica Its molecule can be described as a benzene molecule with two adjacent hydrogen atoms replaced by an unsaturated lactone ring −(CH)=(CH)−(C=O)−O−, forming a second six-membered heterocycle that shares two

So Hg 2 Cl 2 it the lowest whole number ratio of cation to anion. This new addition to a line of opulent perfumes presents an alluring blend that marries the sweetness of caramel with an enticing smokiness. The bottle of 1 Million Elixir has the exact shape of a gold bar, just like its predecessors, now with the triangle plate carrying the engraved number 1. Coumarin (/ ˈ k uː m ər ɪ n /) or 2H-chromen-2-one is an aromatic organic chemical compound with formula C 9 H 6 O 2. The flower for 2023 is NARCISSE. Paris by Azalea Parfums is a fragrance for women and men. Perfumes and colognes from fashion houses and perfume designers. 3. Adr-ett je predstavljen 2015. The nose behind this fragrance is Olivier Pescheux. CK be was launched in 1996. 77. The nose behind this fragrance is Alienor Massenet. . Sì Intense 2021 was launched in 2021. Nomenclature. However, her fragrance brand, which is. Bad Boy was launched in 2019. It's truly an honor to be reviewed by the best journalists in the industry. The principles of naming vary from the relatively informal conventions of everyday speech to the internationally agreed principles, rules and recommendations that govern the. Tag: NOMENCLATURE FRAGRANCES. Alfred Dunhill fragrances were made in collaboration with perfumers Ron Winnegrad, Gerard Anthony, Michel Almairac, Alain Astori, Maurice Roucel, Michel Girard, Frank Voelkl. In Chemistry’s case this would also include devices, tools, apparatus, instruments, etc. Back to the roots, is the motto for the new fragrance CR7 Origins, from the Portuguese football player Cristiano Ronaldo. Efflor-esce by Nomenclature is a Floral fragrance for women and men. CK be by Calvin Klein is a Floral Woody Musk fragrance for women and men. Example sentence: “In scientific research, it is crucial to call a spade a spade and use precise nomenclature to avoid any confusion or misinterpretation. for women and men. [1] Of these 3,059 ingredients, some have evidence. The shades of red are linked to scents that exalt sensuality and desire, most often with amber or gourmand notes. Described as intensive and sophisticated, it is the sequel of successful 2005 firstling Dior Homme and of summer edition Dior Homme Cologne which has been represented in 2007 as well. The bane of perfumephiles' existence is their favorite scents getting discontinued or reformulated. Layton was launched in 2016. A pleasant surprise in 2021 was Laboratorio Olfattivo's Vanagloria, a fluctuating vanilla amber perfume of shifting faces. Minted by Nomenclature is a Aromatic Green fragrance for women and men. Perfume sillage: 2. night. Predict the charge on monatomic ions. This is how I became acquainted with the brand Precious Liquid,. The ester is therefore isopropyl benzoate (both the common name and the IUPAC name). Nomenclature’s lexicon of object names, arranged hierarchically within functionally defined categories, has become a de. Although the retail price is £220, you can get this on discount for as low as £190 and keep in mind this is a 60ml attar (oil) so it will last for YEARS even if you use it daily. Fragrantica® Trends is a relative value that shows the interest of Fragrantica members in this fragrance over time. 10/28/23 07:18 5. Jul 1, 2012. We have more beautiful perfumes to share – by Elena Vosnaki, Sveta, and Nayeli! Fragrantica Team wishes you a Joyful and Blissful Holiday Season,   Merry Christmas and a Happy New Year! The year 2021 has gone down for me as the year I pretty much didn't go to any store, due to the pandemic. Challenging and seductive in a subtle way, like a lady who exudes elegance and style, seducing and not revealing much. Lumira Soleil Du Maroc Parfum unisex 2020. C 3 H 8 = propane = three hydrogen. Paris was launched in 2019. Anamcara means sweetheart in Celtic. a system for naming…. The scientific name consists of two parts. spring.   After a temporary pause in launches that perfume brands (especially niche ones) have taken due to the pandemic, the year 2022 has become especially prolific. 10 Classic Bargain Perfumes You Can't Miss The-scented-rooster. Born in Russia, Elena studied Slavic languages and literature in Moscow before moving to Sarajevo and Belgrade, where the idea for Fragrantica was born. 2. As the Editor-in-Chief, Elena's primary responsibility is to ensure. e Learning Objective is to name halogenated hydrocarbons given formulas and write formulas for these compounds given names. Fragrance Twitter cannot get enough of Italian perfumer Hilde Soliani’s dessert-y and decadent gourmands, especially the cafe-inspired scents like Buonissimo. Aromatic Aquatic. Montblanc Mugler Narciso Rodriguez Natura Nishane O Boticário. Compositions of this group include accentuated green notes of grass or leaves, besides aromatic components (lavender, rosemary, wood). Compositions of this group include fresh accords of sea water and are mostly found as fragrances for men. While natural essences bask in the limelight, synthetics are the clandestine infiltrators. #12. C 2 H 6 = ethane = two hydrogen-saturated carbons. Designer Jean Paul Gaultier has 152 perfumes in. | Meaning, pronunciation, translations and examples2. However, among this ocean of fragrances and people, some illustrations come to mind. Figure 15. Sergey talks with the founders of the brand Nomenclature. The nose behind this fragrance is Alberto Morillas. These rules, used worldwide, are known as the IUPAC System of Nomenclature. for men. With a background in web development and a personal interest in fragrance, Zoran has been instrumental in creating and maintaining Fragranticas online platform. In the context of nomenclature, this phrase highlights the significance of accurately naming things. We keep our readers in the know about the latest perfume releases, renowned fragrances, and hidden aromatic treasures. Top notes are Aldehydes, Pink Pepper and Bergamot; middle notes are Heliotrope, Hawthorn and Lily-of-the-Valley; base notes are Vanilla, Ambrette (Musk Mallow), Peru Balsam and Sandalwood. You should have access to the information others want to share. Ecuación Natural Pulupa unisex 2021. 34 out of 5 with 219 votes. Orb-ital was launched in 2015. Top notes are Galbanum, Violet and Cassis; middle notes are Jasmine, Iris, Rose and Ylang-Ylang; base notes are oak moss, Vetyver and Sandalwood. TREND. It participates in its flavorous minty, lactonic and rough green perfume profile. The fragrance name Tobacolor has the ring. Named after kumarù, the word for the tonka bean tree. Perfume rating 4. 54 Carved Oud Thameen (Unisex) 4. nomenclature. 77 out of 5 with 3,143 votes. Top note is Clementine; middle notes are Magnolia, Ylang-Ylang and Peony; base notes are Vanilla, White Musk and Benzoin. The nose behind this fragrance is Jérôme Epinette. Gabrielle was launched in 2017. They are the building blocks of a fragrance and contribute to its overall scent profile. unisex Save Today! Shop for Nomenclature. ) Themes such as milky flowers, color as expressed in smell, specific flower accords, and. In our base the Aromatic Aquatic group has 98 for women, 471 for men and 370 shared fragrances. "What could be the metaphor for holy_wood. 9: Nomenclature of Simple Compounds. In other words, if there is methyl group located on the second carbon of a. The ability of carbon to combine with large number of elements especially O, N, S, X etc, to undergo catenation to form chains of varying lengths and shapes and existence of isomers has led to the formation of more than five million organic compounds. Fragrantica writer and our rock star from NYC, Patric, shares his favorite fragrances of 2022. A big star from the American scene, Queen Bey has cemented herself through years of being on the frontline. This nomenclature will be discussed when it is possible for a functional group. In its pure form, it smells intense and even acrid. One underlying concern that arose throughout the analysis was the variation in medication nomenclature. A drug generally has thr ee different categories of names from its discovery to the arrival in the market: chemical name, non-proprietary name and. net Printed on November 25, 2001 1 Introduction How often did you try to understanda theorem in a book, but just couldn’t gure out what all those strange symbols were all about? The nomencl package should help authors format a nomenclature. God Is A Woman by Ariana Grande is a Amber Floral fragrance for women. Sauvage Elixir Serge Lutens Tobacco Vanille Tom Ford Valentino Versace. 99 USD. 2. 5. psy-cou was launched in 2019. I lean towards scents which are relatively easier to wear, and features notes I personally like, and in a less avant garde. Fleur de Peau Eau de Parfum was launched in 2018. (B) Citrus fruits like grapefruit contain citric and ascorbic acids. Fragrantica Team wishes you a Joyful and Blissful Holiday Season, Merry Christmas and a Happy New Year!. In this latest edition of Fragrantica Talks, Nicola, John, and Adam try to define what can make a perfume composition "dark" and identify dark perfume notes. The three basic commands to produce the nomenclatures are: makenomenclature. The floral group is said to be more youthful and feminine. The nose behind this fragrance is François Demachy. for women and men. The selection of the best fragrances of 2022 by Fragrantica editor and translator Sergey Borisov. printnomenclature • Put printnomenclature at the place you want to have your nomen-clature list. Nobody Knows (Into The Woods) by Fuffancs. Gentle Fluidity Silver was launched in 2019. Top 20 Fragrantica's highest rated fragrances with at least 1000 votes: 4. 3. 8. Angel Nova by Mugler is a Amber Floral fragrance for women. Gentle Fluidity Gold was launched in 2019. Cadaqués. 04 out of 5 with 25 votes. Fragrantica® Trends is a relative value that shows the interest of Fragrantica members in this fragrance over time. The light blues translate fresh, aquatic, and versatile perfumes, while the dark blues refer to the night, sophistication, and mystery. The nose behind this fragrance is Patricia Choux. It's also a year. 1 12. Nomenclature, a collection of rules for naming things, is important in science and in many other situations. The brand offers a variety of other fragrances, including Ultra Male, Le Beau, Classique, Scandal A Paris, Scandal By Night, Scandal Pour Homme, Scandal, La Belle, and Le Male. Musc K was launched in 2023. Coromandel Parfum was launched in 2019. With its hypnotizing beauty and heady perfume, narcissus symbolizes renewal and rebirth. The stem names are suggestive of the structure or the composition of the material, e. a system for naming things, especially in a particular area of science: 2. The meaning of NOMENCLATURE is name, designation. DGAF by BORNTOSTANDOUT® is a fragrance for women and men. 1. Fenty was launched in 2021. Coty, Inc. Naming ionic compound with polyvalent ion. Example: The scientific name of the man is Homo sapiens. 🥀Nomenclature- Neo Rose the black tea and pink pepper notes tho 😳 27 Apr 2023 23:33:30New Fragrances. Elena Knezevic is the Editor-in-Chief and co-founder of Fragrantica, which she started with Zoran Knezevic in 2007. If you own such a car, house the fragrance inside it, they complement each other. Perfume rating 4. This is a new fragrance. L'Interdit Eau de Parfum was created by Dominique Ropion, Anne Flipo and Fanny Bal. 33 out of 5 with 64 votes. Perfumes and colognes from fashion houses and perfume designers. All of these fragrances are described as intense, addictive, and indulgent, with unique and captivating scent profiles. On Cristiano Ronaldo's website, it says, "Authentic. Several other examples of this nomenclature are shown in Table 5. Patricia Choux Perfumes. Course: Chemistry library > Unit 1. Greater detail canLe Male Le Parfum Maison Francis Kurkdjian Maison Martin Margiela Mancera Memo Paris Montale. The most straightforward definition is that an acid is a molecular compound that contains one or more hydrogen atoms and produces hydrogen ions (H+) ( H +) when dissolved in water. This is a new fragrance. Perfumes Search - Fragrantica: Your Online Destination for All Things Fragrance Discover the world of perfumes with Fragrantica, a comprehensive online resource, magazine, and community dedicated to fragrance enthusiasts. Predict the charge on monatomic ions. Beth Carsten Fragrantica Writer & Editor. 4 oz for Female Free shipping, arrives in 3+ days About Nomenclature Perfume for Women in Fragrances -. His List of New Guinea Birds deals with the biogeography of those birds, as well as with their systematics and nomenclature. The nose behind this fragrance is Francis Kurkdjian. Ushirā Parfums Karmic Hues. Introducing Nomenclature, a collection of four unique scents made out of 100 percent synthetic materials—a reminder to all raw fragrance materials out there that these fictitious brothers and. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Topic Questions and revision materials for Save My Exams. Scent resources, perfume database, and advertisement historical records. 25 out of 5 with 11,494 votes. Dark Velvet Oud by umma toga. Perfume rating 3. And let's start with the simplest alkyne, a two carbon alkyne-- so a triple bond between two carbons, like that. Essential oil of angelica is obtained from the roots, and other parts of the plant are used to flavor food and beverages. 02/05/23 14:00:00 ( 37 comments ) Armani announced the launch of the new Armani Code Eau de Toilette (2023). The announcement of the fragrance we already published a while ago. Sauvage Elixir Serge Lutens Tobacco Vanille Tom Ford Valentino Versace. The nose behind this fragrance is Marie Salamagne. We keep our readers in the know about the latest perfume releases, renowned fragrancLet us learn to prioritize. Armaf Aura Fresh. It begins as a deceptively linear, smoked vanilla. Carboxylic Acids, RCO 2 H. 1. We'll save money in our pocket, one's health (so many added scents cause chemical build-up), and our nose, too. Shiso belongs to the mint family. Moderately sweet, it does not overdo it with sugar. For example, when the gas HCl HCl (hydrogen chloride) is dissolved in water, the solution is called hydrochloric acid. Looks no further. for women. The IUPAC nomenclature system is a set of logical rules devised and used by organic chemists to circumvent problems caused by arbitrary nomenclature. Eros Flame by Versace is a Woody Spicy fragrance for men. 51 out of 5 with 63 votes. Perfume rating 3. 54 Allure Homme Edition Blanche EDP Chanel (Male) 4. 1 The basics of this nomenclature are shown here, and in companion documents on the nomenclature systems for organic chemistry2 and polymers,3 with hyperlinks to the original documents. Of course, the results of any competition in art. Almond cream and flower petals, sweet flower core, and milky coffee. g. Armaf omenclature • Issue the omenclature command (see Section2. The newest variation of the iconic 1 Million fragrance comes in 50ml and 100ml Parfum Intense, expected in stores in late January 2022. The best perfume choices by Fragrantica. Described by loyal users as "rich, indulgent, warm, spicy and downright. Lattafa Perfumes perfumes and colognes. A touch of a watery green note is discernible in its otherwise smooth and soft woody trail. 8. The makenomenclature command is required for the generation of the nomenclature file (. Basenotes - frequent maintenance overhauls and slowness of system. Tobacolor was launched in 2021. Alcohols with one to four carbon atoms are frequently called by common names, in which the name of the alkyl group is followed by the word alcohol:. night. The naming process for 2-chlorophenol (o-chlorophenol). 4. 67 out of 5 with 2,919 votes. Voce Viva was launched in 2020. 00 out of 5 with 2 votes. 2: Overview of the IUPAC Naming Strategy is shared under a CC BY-NC-SA 4. Fragrantica® Trend je relativna vrednost koja pokazuje interesovanje članova Fragrantice za ovaj miris tokom vremena. District of Nolo by Trussardi is a Floral Fruity fragrance for women and men. 9, is announcing a new, luxurious edition which arrives on the market before Christmas holidays 2009, Bond No. Stepping off the sharpest edges of the pandemic, we reclaimed social contact via wearing masks on and off, meeting friends in outdoor activities,. new. 99 USD. night. night. Usually put right after importing the package. Top notes are Pink Pepper, Italian Mandarin and Grapefruit; middle notes are Cinnamon, Cardamom and Cypress; base notes are Tonka Bean,. Original Penguin 8. Naming ionic compound with polyvalent ion. IUPAC is the universally-recognized authority on chemical nomenclature and terminology and two IUPAC bodies take leading roles in this activity: Division VIII – Chemical Nomenclature and Structure Representation and the Interdivisional Committee on Terminology, Nomenclature, and Symbols. popularity. Exercise 2. He reminisces about the pungent odors of the barnyard and the fresh rain at his uncle's farm that left a lasting. You by Glossier is a Floral Woody Musk fragrance for women and men. A compound containing a benzene ring which has one or more alkyl substituents is called an arene. In this episode, cohost Adam sits down with cohost Nicola to discuss her discoveries at Esxence 2023, one of the most prestigious fragrance trade shows in the world. FragranceNet. If there is a choice, give priority to the functional group over the substituents. Let's take a closer look at the 49th Amendment, i. Perfume rating 3. ) A stem name (Table 12. DefineMe Fragrance Ariel Disney Princess Perfume Purse Spray 0. draw the Kekulé, condensed or shorthand structure of an alkane, given its IUPAC name. Tìm hiểu thêm. The most effective way of giving this information is discussed, and more details of cis and trans follow in Section 7. Common polyatomic ions. At the top.   2022 saw the rise of new creativity in perfumery, as many smaller trends surfaced: depictions of colors and sensations (moving away from the usual postcards from distant shores. Worked example: Finding the formula of an ionic compound. Sculpture Parfum was launched in 2022. 95 USD. The naming of cycloalkanes follows a simple set of rules that are built upon the same basic steps in naming alkanes. Trans-2-hexenol is somewhat reminiscent of an unripe banana peel – leafy, fruity, waxy. This is a new fragrance. The earliest edition was created in 1934 and the newest is from 2022. 1905 was launched in 1905. L'Imperatrice Limited Edition by Dolce&Gabbana is a Floral Fruity fragrance for women. Projection: 9/10. Etat Libre d'Orange 53. The nose behind this fragrance is Christophe Raynaud. Perfumes Search - Fragrantica: Your Online Destination for All Things Fragrance Discover the world of perfumes with Fragrantica, a comprehensive online resource, magazine, and community dedicated to fragrance enthusiasts. Nomenclature - IUPAC Introduction & Common Names. SILLAGE. Zara. Nomenclature Minted is available at Aedes, $90 for 20 ml Eau de Parfum or $175 for 75 ml. OUAI 5. This year, my fragrance. Figure 7. Cis-3-hexenol aka leaf alcohol is a very popular green perfume material with a fresh grassy smell. The nose behind this fragrance is Christi Meshell. Angelica refers to the genus of species with more than 60 members. The editor and writer of Italian Fragrantica, Lucia Remigi, shares her best fragrances of 2022. In addition to simple benzene naming and OMP nomenclature, benzene derivtives are also sometimes used as the "parent" in the name of a larger compound. It creates an intimate, skin scent bubble, just as if you were out of the shower and you could smell your clean skin, still reminiscent of shower gel. Frank Voelkl is a Senior Perfumer at Firmenich, with over 20 years of experience in the fragrance industry. The earliest edition was created in 2015 and the newest is from 2022. 12 out of 5 with 3,424 votes. A phenyl group consists of a benzene ring with one of its hydrogens removed. The –e ending is removed from the name of the parent chain and is replaced -oic acid. ESXENCE 2022: Along the Esxence Maze – Angela Ciampagna, Nomenclature, and Goldfield & Banks Australia. Nomenclature Minted unisex 2022. summer. The nose behind this fragrance is Nicolas Bonneville. Top notes are Pineapple, Cassis, Mango, Peach, Pear, Apple and Orange; middle notes are Saffron, Almond, Rose and Jasmine; base notes are Amber,. Perfume rating 3. Montblanc Mugler Narciso Rodriguez Natura Nishane O Boticário. Generations of chemists have learned – sometimes grudgingly – to read and write systematic names for organic compounds using guidelines codified by the International. 1905 by Detaille is a Chypre Floral fragrance for women. (Some of the names we used earlier, such as isobutane, isopentane, and neopentane, do not follow these rules and are called common names . nomenclature. Little Mermaid Princess Ariel EDT Spray For Girl 3. It was designed so that every chemical structure has its own unique, unambiguous name. 9 Perfume by Bond No 9 is a Amber Floral fragrance for women and men. Uomo Salvatore Ferragamo Signature by Salvatore Ferragamo is a Leather fragrance for men. Top notes are Strawberry, Raspberry, Blackberry, Sour Cherry, Black Currant, Mandarin Orange and Lemon; middle notes are Violet and Jasmine; base notes are Musk, Vanilla, Cashmeran,. Signature was launched in 2020. “Give Credit Where Credit Is Due”. Orb-ital was launched in 2015. Derive names for common types of inorganic compounds using a systematic approach. summer. 91 out of 5 with 11,888 votes. Fame was created by Dora Baghriche, Marie Salamagne, Alberto Morillas and Fabrice Pellegrin. 93 out of 5 with 1,701 votes. Now that you know simple alkane nomenclature and various functional groups, we can begin to discuss more complicated systems. Examining the cultural context of blue fragrances, especially for men. Alkenes contain carbon-carbon double bonds and are unsaturated hydrocarbons with the molecular formula is C n H 2n; this is also the same molecular formula as cycloalkanes. The IUPAC system of nomenclature assigns a characteristic suffix to these classes. Rose Blanche Precious Liquid. English Translation of “NOMENCLATURE” | The official Collins French-English Dictionary online. 20 comments. Citruses provide a refreshing and effarvescent quality to fragrances, accounting for the top note which tickles our noses with pleasure. Nomenclature Efflor Escen. 4. In short, it is a smooth lavender-vanilla-leather fragrance. The nomenclature of drugs is a complex process. أول عطر صدر في عام 2015 وأحدث إصدارت الدار عام 2022. 4. Classical molecules occur when nonmetals form covalent bonds with each other and this can get very complicated. Niece Allegra Versace is 50% owner of the company. Tim Soderberg. Branched alkanes C n H 2n+2 = suffix -ane. Fragrantica® Trends is a relative value that shows the interest of Fragrantica members in this fragrance over time. The nose behind this fragrance is Annick Menardo. Whispers in the Library was launched in 2019. Elena Knezevic is the Editor-in-Chief and co-founder of Fragrantica, which she started with Zoran Knezevic in 2007. The root name tells you the length of the molecule's parent chain, which contains the parent functional group. Fragrance Du Bois 47. . Fragrantica® Trends is a relative value that shows the interest of Fragrantica members in this fragrance over time. Of the interesting new perfumes with green notes, I would note Arcadia Hiram Green, Fatamorgana 1907, Yellow Splash Attar al Has, M. Top notes are Blueberry and Tangerine; middle notes are Bulgarian Rose, Geranium and Magnolia; base notes are Musk and Patchouli. Its elder brother, 5-methyl furfural, is also used in perfumery; it has a sweetish caramel odor of burnt sugar with coffee, pastries, spices, and maple syrup nuances. night. Perfume sillage: 2. This is a new fragrance. 4. 12 out of 5 with 16 votes. Chemical nomenclature is far too big a topic to treat comprehensively, and it would be a useless diversion to attempt to do so in a beginning course; most chemistry students pick up chemical names and the rules governing them as they go along. g. Designer Jean Paul Gaultier has 152 perfumes in. SILLAGE. Sentence Examples. Heralding springtime, it ends the reign of winter frost. Essential Parfums 9. 20 out of 5 with 3,152 votes. Heart: mimosa, jasmine, rose, lily of the valley. The simplest aldehydes, formaldehyde and acetaldehyde, have very aggressive and unpleasant smells and nevertheless, flavourists use acetaldehyde for some of their flavours. However, most chemists do not consider these items to be under chemical nomenclature, but rather chemical. I. Sauvage Elixir Serge Lutens Tobacco Vanille Tom Ford Valentino Versace. The nomencl package implements a few basic commands to do that. 1. Cis-3-hexenol aka leaf alcohol is a very popular green perfume material with a fresh grassy smell. Tacotyme. Angelica archangelica, or garden angelica as it is commonly known, has sweetly-scented edible stems, but bears a close resemblance to several poisonous plants. 10/21/23 15:54:31 ( 44 comments ) In part two of our fall series , autumn is in full swing: leaves are falling, pumpkins are being carved, cider. Learn more. This module describes an approach that is used to name simple ionic and molecular compounds, such as NaCl, CaCO 3, and N 2 O 4.   I guess 2022 was somewhat of a transitional year, both in the world in general and in the realm of perfumery. Nomenclature launched a new extremely attractive line aimed at gen Z. Shop. For The First Time On The Stage: LoubiHorse. District of Nolo was launched in 2023. Par exemple, la nomenclature additive de POCl3 (ou PCl3O, trichlorure de phos-phoryle en nomenclature de composition. But we can hardly talk about chemistry without mentioning some chemical substances, all of. With its cucumber-cool, earthy, slightly skin-like facets contrasting with. Guerlain has always used luxurious and rare materials for its perfumes,.